Abstract

Abstract Vapor from liquid ethylene dibromide (EDB) is presented as an alternative to anhydrous HCl for in situ gas phase etching of InP substrates in Metalorganic Vapor Phase Epitaxy (MOVPE). The etch rate and surface morphology behaviors have been determined for conditions useful as a substrate cleaning step prior to growth of InP and InGaAs epilayers. The thermally activated decomposition and etching are analogous to III–V semiconductor growth processes; and the behavior in different carrier gas mixtures demonstrates dependence on gas phase reactions in the heated vapor above the substrate.

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