In Situ Upgrading of Athabasca Bitumen Using Multimetallic Ultradispersed Nanocatalysts in an Oil Sands Packed-Bed Column: Part 1. Produced Liquid Quality Enhancement

Abstract

Conventional crude oil production is declining, while the consumption of petroleum-based fuels is increasing. Therefore, bitumen and heavy oil exploitation is steadily growing. However, in the present context, heavy oil and bitumen exploitation processes are high-energy and water-intensive and, consequently, have significant environmental footprints because of the production of gaseous emissions, such as CO2, and generating huge amounts of produced water. In situ catalytic conversion or upgrading is a promising cost-effective and environmentally friendly technology that aims at reducing the environmental footprints of oil sand exploitation and producing of high-quality oil that meets pipeline and refinery specifications. In this study, in situ prepared Ni–W–Mo ultradisperse nanocatalysts within a vacuum gas oil matrix were used for Athabasca bitumen upgrading in a packed-bed flow reactor at a high pressure and temperature. Experiments were performed at a pressure of 3.5 MPa, temperatures from 320 to 340 °...