In situ synthesis of carbon-coated aluminum nanoparticles by argon protective arc ablation in the liquid nitrogen environment

Abstract

The preparation and storage of aluminum nanoparticles pose significant challenges due to their high chemical reactivity. This paper proposes a one-step method for the production of carbon-coated aluminum nanoparticles using an argon protective arc in a liquid nitrogen environment. The emission spectra of the arc validate that the method proposed in this paper can effectively mitigate the adverse impact of impurity gases such as oxygen and water on the product without the need for expensive vacuum equipment. The obtained nanoparticles underwent characterization through high-resolution transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Raman analysis, thermogravimetric analysis, and dynamic light scattering. The characterization results demonstrate the successful synthesis of carbon-coated aluminum nanoparticles with nitrogen-doped fullerene shells. With an increase in arc current, the nanoparticles exhibit a corresponding enlargement in diameter, accompanied by a broader distribution. The characterization of the electrode erosion suggests that the aluminum droplet ejection plays a more important role in the nanoparticle generation process as the arc current increases. Optimized strategies are proposed to increase the percentage of successfully-formed carbon-coated aluminum nanoparticles.