Abstract

Crystallization of YBa 2Cu 3O x via the peritectic reaction; Y 2BaCuO 5 + Liquid → YBa 2Cu 3O x was successfully observed in situ by high temperature optical microscopy. It was found that the growth of YBa 2Cu 3O x crystals proceeds with the aid of the peritectic reaction, which is different from the normal peritectic reaction of the binary alloy system. The present results give us an important clue how to grow a high quality YBa 2Cu 3O x single crystal from the high temperature solutions.

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