Abstract
Photoelectron spectroscopy for chiral discrimination is routinely performed for low photoelectron kinetic energies (PKEs), whereas it is considered impossible for high PKEs. We demonstrate theoretically that chiral photoelectron spectroscopy for high PKEs is possible using chirality-selective molecular orientation. The photoelectron angular distribution associated with one-photon ionization by unpolarized light can be characterized by a single parameter, β. We show that most other anisotropy parameters are zero when β is 2, as is often the case in the high PKEs. Exceptionally, odd-order anisotropy parameters are increased by a factor of 20 by orientation, even for high PKEs.
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