Abstract
The ab initio molecular orbital approach suggested that polysilane oligomer has a tendency to prefer a trans zigzag-type structure rather than a random structure when the molecule is charged. Such unique behavior in the rotational barrier of charged polysilane has the potential for a description of solvatochromic transition in conformation of the Si main chain in poly[bis(4-propoxybutyl)silylene] when acids are added.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of Polymer Science Part A: Polymer Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.