Imaging of ASR Gel by Soft X-Ray Microscopy

Abstract

The soft x-ray transmission microscope XM-1 was used to examine alkali-silicate reaction (ASR) gel morphology in an experimental investigation of the alkali-aggregate reaction (AAR). The XM-1 microscope is operated by the Center for X-ray Optics on beamline 6.1 of the Advanced Light Source, a third generation synchrotron radiation facility operated by the Ernest O. Lawrence Berkeley National Laboratory. The instrument is unique as samples can be observed wet, with high resolution (43 nm), over time, as chemical reactions proceed. Soft x-ray microscopy was used to examine the in situ reaction of ground ASR gel, obtained from a large dam, and solutions of sodium hydroxide, calcium hydroxide, and combined sodium and calcium hydroxide. From this investigation, it appears that ASR gel combines with alkalis present in pore solution to produce a reaction gel capable of swelling, while the reaction of the ASR gel in the presence of calcium hydroxide and no alkalis results in the formation of a structure resembling C-S-H. It is theorized that the formation of C-S-H or a related compound will decrease the degree of swelling that would otherwise result from the formation of an alkali-aggregate reaction product. The C-S-H-like structure may also contribute strength. These hypotheses are currently under investigation.