Identification of Triazine UV Filters as an Emerging Class of Abundant, Ubiquitous Pollutants in Indoor Dust and Air from South China: Call for More Concerns on Their Occurrence and Human Exposure.

Abstract

Triazine UV filters are an important class of UV filters, but knowledge on their environmental occurrence and human exposure remains largely unknown. In this study, we performed a targeted analysis of 17 emerging triazine UV filters in indoor dust and indoor air from South China based on a newly developed LC-MS/MS method. A total of 12 of the 17 emerging triazine UV filters were first positively detected in the dust and air samples. Ethylhexyl triazone (EHT) and bis-ethylhexyloxyphenol methoxyphenyl triazine (BEMT) were identified as the most abundant compounds. The median total concentrations of triazine UV filters reached 3860 ng/g in indoor dust and 1590 pg/m3 in indoor air. Gas-particle partitioning analysis showed that triazine UV filters were predominant in the particle phase in ambient air. Significant concentration correlations were observed among most triazine UV filters. The estimated daily intake of triazine UV filters through dust ingestion and air inhalation for toddlers under high-end exposure scenarios was up to 839 ng/kg bw/day, but a lack of toxic thresholds hampers accurate risk assessment. Our work highlights another emerging class of UV filters that significantly contribute to indoor chemical mixtures and expresses concerns over their occurrence and human exposure.