Hyperporous magnetic catalyst foam for highly efficient and stable adsorption and reduction of aqueous organic contaminants

Abstract

The facile and low-cost fabrication of free-standing magnetic catalysts with high catalytic efficiency, rapid reaction rate and excellent recoverability has been pursued for various catalysis applications, e.g., treating aqueous organic 4-nitrophenol pollutants. Here, we design and fabricate a free-standing nickel-coated hyperporous polymer foam (Ni-HPF) with adjustable shapes and sizes, hierarchical multiscale porous structures, abundant catalytical interfaces and excellent super-paramagnetic properties. Due to the synergistical effect of abundant binding sites and highly catalytic reduction, the as-prepared Ni-HPF has demonstrated high conversion efficiency (> 90% at extremely low concentration of 7.5 μM) and rapid reaction rate (2.58 × 10−3 s−1) for the reduction of organic 4-nitrophenol. Moreover, the magnetic catalyst also holds excellent recoverability (>80% conversion rate even after 1000 cycles) and good reproducibility (>80% conversion rate after 3 months of storage). As such, this work with novel material design and working principle could provide a wide range of potential applications in water purification, chemical catalysis and energy storage devices.