Abstract
A series of novel stannosilicates with the MWW topology, Sn-MWW, was hydrothermally synthesized in alkali medium using boric acid as a crystallization-supporting agent. The Sn-MWW lamellar precursors with a high crystallinity were obtained from the synthetic gels even at Si/Sn ratio of 60. UV–visible and 119Sn MAS NMR characterizations verified that the Sn species were incorporated in the framework, occupying mainly the tetrahedral sites. A mild acid treatment was conducted on the precursors to induce a structural transformation to tin-containing materials structurally analogous to MCM-56. Sn-MCM-56 thus post-synthesized comprised partially delaminated MWW sheets, and possessed larger external surface as well as more open reaction space. Sn-MCM-56 analogue alleviated effectively the steric restriction and diffusion limitation to bulky molecules that the microporous zeolite catalysts usually encountered. It appeared to be more efficient than Sn-MWW in the Baeyer–Villiger oxidation of 2-adamantanone with H2O2. Moreover, Sn-MCM-56 turned to be more active than Sn-Beta when tert-butyl hydroperoxide was employed as an oxidant.
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