Abstract
A carboxylate-bridged metal–organic coordination polymer {[Ni2(NA)4(μ-H2O)]·2H2O}n (1, HNA=nicotinic acid) has been synthesized under hydrothermal conditions and characterized by FT-IR, TG/DTA, micro analysis and single-crystal X-ray diffraction. 1 has an interesting 3D network structure and adjacent networks are further connected together via strong π–π packing interactions. The thermal behavior and catalytic performance of 1 were investigated and its selectivity was measured as 100% for the oxidation of thymol (T) to thymoquinone (TQ).
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