Abstract
Having a gas: Topotactic exchange (65 %) of γ-zirconium phosphate with terphenyldiphosphonic acid yielded a pillared material with a specific area of 90 m2 g−1. Subsequent treatment with hypophosphorous acid afforded a material of α type, with no incorporated hypophosphite and a specific area of 400 m2 g−1, which took up 74 cm3g−1 of H2 at 650 Torr and 77 K.
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