Hydrogen sorption hysteresis and superior storage capacity of silicon-carbide nanotubes over their carbon counterparts

Abstract

We report for the first time the results of an extensive experimental study of hydrogen sorption in silicon-carbide nanotubes (SiCNTs), which were synthesized using the reaction between SiO vapor and carbon nanotubes (CNTs) in an argon atmosphere in the temperature range 1200 °C–1500 °C. The as-synthesized SiCNTs were then purified using a sodium hydroxide solution in order to remove the side products of the synthesis reaction. The hydrogen sorption characteristics of the as-synthesized SiCNTs, as well as those of the purified SiCNTs were then measured at 25 °C and for pressures of up to 100 bars. The results reveal hysteresis between the adsorption and desorption isotherms, which we attribute to the presence of metal impurities and/or the multilayer structure of the nanotubes. The hydrogen storage capacity of the as-synthesized SiCNTs is similar to that of the CNTs, whereas for the purified SiCNTs it is 50% higher than that of the CNTs, in agreement with the results of molecular simulations reported previously. In addition, the hydrogen uptake rate in the SiCNTs is about five times faster than that in the CNTs and, in contrast with the CNTs, its desorption from SiCNTs is completely reversible under vacuum.