Abstract
Ni/γ-Al2O3, Ni/AlSBA-15 and Ni/HZSM-5 catalyst with small amount of active metal of 1 wt% Ni loading were prepared. The performance for hydrodeoxygenation upgrading of a model bio-oil was evaluated under different reaction conditions. It was found that Ni/γ-Al2O3 displays the highest anisole conversion 60% at WHSV = 81.6 h−1 and nearly 100% at WHSV = 20.4 h−1 as compared with Ni/AlSBA-15 and Ni/HZSM-5. Toluene, a premium aromatic product, could form and the maximum toluene selectivity 20% could be obtained at WHSV = 20.4 h−1 at 3 bars over Ni/HZSM-5. 10% n-hexane selectivity could be obtained over Ni/HZSM-5 at WHSV = 20.4 h−1 at 3 bars. 70% arene selectivity could be obtained at WHSV = 81.6 h−1 at 3 bars over Ni/HZSM-5.
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