Abstract

Rate constants have been measured for the coupling between hexenyl radicals and 2,2-dimethylhexenyl radicals and electrogenerated anion radicals of anthracene, 9,10-diphenylanthracene, benzophenone and quinoxaline. The rate constant for all four reactions in N,N-dimethylformamide is log k 2 =9.1(5), which is in accordance previous results in 1,2-dimethoxyethane for naphthalene and benzophenone anion radicals and 1-hexenyl radicals. The conclusion is that the coupling reaction between aromatic anion radicals and alkyl radicals has all the characteristics of a radical-radical coupling

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