Abstract
AbstractAn efficient highly regio‐ and stereoselective copper(I) chloride‐mediated carbometallation of differently substituted 2,3‐allenols with primary or secondary alkyl or aromatic Grignard reagents followed by iodination to synthesize fully‐substituted allylic alcohols has been developed. This protocol introduces the R4 group from the Grignard reagent to the terminal position of the 2,3‐allenols.
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