Abstract
Vapor deposition polymerization was carried out by supplying sebacoyl dichloride monomer at a regular interval from an external vacuum system, while 1,10-diaminodecane monomer was evaporated at a constant speed throughout the experiment. The alternate reaction of the two monomers epitaxially on the substrate, where the diamine molecule had already been deposited with perpendicular orientation, resulted in the formation of polyamide thin films with almost perfect molecular orientation perpendicular to the substrate.
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