Abstract
We utilized a modified reverse-microemulsion method to develop highly emissive and photostable zero-dimensional (0D) Cs4Pb(Br1-xIx)6 perovskite nanocrystals (PNCs). We employed single-particle photoluminescence (PL) spectroscopy to explore blinking statistics and demonstrate single-photon emission from individual PNCs. Low-temperature blinking and photon correlation studies revealed a transition from single- to multiphoton emission with progressively longer "delayed" PL components, reaching ∼70 ns at room temperature and representing a distinctive behavior to previously known iodide PNCs. Such thermally activated PL emission is explained by the existence of defect-related "reservoir" states, feeding back into the PNC's emissive state and providing multiple photons within a single excitation cycle. This work establishes a new member in the 0D class of perovskite materials, studies its photophysical properties, and reveals its potential for future optoelectronic applications.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
