Abstract
Reaction of cobalt(II) phthalocyanine (CoPc) with thionyl chloride and with bromine leads to the formation of CoPcCl2 and CoPcBr2, respectively; magnetic i.r., oxidative titration, and e.s.r. data indicate these complexes to contain a phchalocyanine radical species, characterised in the solid state for the first time.
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