Abstract
The processible and high yield polyborosilazane (PBSZ) precursor for SiBN ceramics was prepared by coammonolysis reaction of dichlorosilane and trichloroborazine. The synthesized PBSZ precursor was characterized by Fourier Transform Infrared spectroscopy (FTIR), 1H, 11B, and 29Si Nuclear Magnetic Resonance (NMR), and its ceramic conversion chemistry was investigated by differential scanning calorimetric (DSC), X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and thermal gravimetric analysis (TGA). The PBSZ precursor is a viscous liquid and changes to an insoluble solid via a cross-linking reaction between the N-H group and Si-H group as post-heated from 60 to 180°C. The insoluble solid is transformed to Si3N4 and BN amorphous structures with an approximately 95% ceramic yield after being pyrolyzed to 1000°C.
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