High-pressure synthesis and ferroelectric properties in perovskite-type BiScO3–PbTiO3 solid solution

Abstract

Stabilization of a perovskite-type solid solution (1−x) PbTiO3–x BiScO3 with x⩾0.45 was demonstrated by high-pressure synthesis, and the phase diagram and the ferroelectric properties of the solid solution were investigated. The crystal symmetry of the perovskite subcell change in turn from tetragonal, to rhombohedral, to pseudocubic, to monoclinic, and then to triclinic as x increases. It was found that the tetragonal, rhombohedral, and pseudocubic phases are ferroelectric, while the monoclinic phase is not. In the morphotropic phase boundary in the vicinity of x=0.37 between tetragonal and rhombohedral phases, the maximum electromechanical coupling factor and the minimum coercive electric field were just like those observed in other Pb-based ferroelectric perovskites. In addition, relaxor behavior in the dielectric constant was observed in the vicinity of x=0.5.