Abstract
A review of the applications of high-performance liquid chromatography to organometallic compounds and metal coordination complexes since 1969 is presented. The review covers high-performance liquid chromatographic separations which have been reported for arene metal carbonyls, cyclopentadienyl metal carbonyls, dicyclopentadienyl complexes, metal cluster complexes, metallocarboranes, cyclopentadienyl-cycloolefin complexes, alkyl and aryl complexes and organopolymetallic compounds. The second part of the review summarizes separations of metal coordination compounds, including complexes of the following ligand types: β-diketonates, β-ketoamines, hydrazones, semicarbazones, dithiocarbamates, dithiozonates, bipyridines, phenanthrolines, 8-hydroxyquinolates, EDTA, ethylenediamines, amino acids, carbonates, camphorates, diphosphonates, crown ethers and porphyrins.
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