Hierarchical Amorphous-Crystalline Ceramic Nanotube Array Nanocomposites with Superior Mechanical and Functional Properties.
Despite extensive efforts to develop high-performance ceramic nanocomposites, specially achieving both high stiffness and high damping remains challenging because these properties are typically mutually exclusive. Here, a bottom-up strategy is developed to fabricate an enamel-inspired ceramic nanotube array nanocomposite by assembling highly ordered amorphous/crystalline-titania nanotube arrays infiltrated with a polymethyl methacrylate matrix on a large scale. This nanocomposite simultaneously exhibits high stiffness (nanoindent Young's modulus: ≈71.4GPa; nanoindent hardness: ≈4.3GPa), high damping (tanδ: ≈0.07), exceptional energy dissipation (≈4.6 µJ µm-3), and excellent fatigue resistance that surpass those of conventional and biomimetic ceramic-based materials, while also offering good processability (can be sculptured into various shapes), biocompatibility (no tissue damage or abnormal immune responses in vivo), and corrosion resistance. The remarkable mechanical performance arises from the robust amorphous/crystalline ceramic nanotube array skeleton and the abundant three-phase interfacial adhesion. This work expands the hierarchical dimensionality of enamel-like material design by precisely tailoring the heterogeneous phases within nanotubes, positioning this nanocomposite as a promising candidate for multipurpose applications that demand exceptional dynamic load-bearing capacity, exemplified by the electronic substrate of a dental patch for oral health monitoring.
- Research Article
170
- 10.1002/adma.201602580
- Sep 30, 2016
- Advanced Materials
A variable stiffness fiber made of silicone and low melting point alloys quickly becomes >700 times softer and >400 times more deformable when heated above 62 °C. It shows remarkable self-healing properties and can be clamped, knitted, and bonded, as shown in a foldable multi-purpose drone, a wearable cast for bone injuries, and a soft multi-directional actuator.
- Research Article
20
- 10.3844/ajassp.2011.610.616
- Jun 1, 2011
- American Journal of Applied Sciences
Problem statement: The advancements in machine tools to maximize the production by increasing spindle speeds have caused vibration in machine tools. The two functional requirements of machine tool bed for machine tools are high structural stiffness and high damping, which cannot be satisfied simultaneously if conventional metallic materials such as cast iron are employed. Hence there is a need to replace cast iron with alternate materials. Approach: The objective of this study is to improve the stiffness, natural frequency and damping capability of machine tool bed using a composite material containing welded steel and polymer concrete. Welded steel material has high stiffness but low damping and polymer concrete has high damping but low stiffness. So in this study, a machine tool bed made of sandwich structures of welded steel and polymer concrete is designed and manufactured. Modal and static analyses were conducted numerically and experimentally to determine the modal frequencies, damping ratio, deformation and strain. Results: The results at first mode showed that the natural frequency improved by 24.7% and damping ratio was 2.7 times higher than cast iron. The comparison of strain and deformation also showed significant improvement. Conclusion: This study proposed a hybrid welded steel bed as a replacement for cast iron as a machine tool bed material and the results showed that the static and dynamic characteristics were superior to cast iron.
- Research Article
50
- 10.1038/mt.2008.239
- Jan 1, 2009
- Molecular therapy : the journal of the American Society of Gene Therapy
Gene-mediated Restoration of Normal Myofiber Elasticity in Dystrophic Muscles
- Research Article
84
- 10.1016/j.ijsolstr.2013.03.018
- Apr 8, 2013
- International Journal of Solids and Structures
Advanced damper with high stiffness and high hysteresis damping based on negative structural stiffness
- Research Article
126
- 10.1016/j.clae.2004.08.002
- Oct 26, 2004
- Contact Lens and Anterior Eye
Tensile properties of soft contact lens materials
- Research Article
5
- 10.1002/jbm.b.33905
- May 5, 2017
- Journal of Biomedical Materials Research Part B: Applied Biomaterials
Here, a new technology was developed to selectively produce areas of high and low surface Young's modulus on biomedical polymer films using micropatterns. First, an elastic polymer film was adhered to a striped micropattern to fabricate a micropattern-supported film. Next, the topography and Young's modulus of the film surface were mapped using atomic force microscopy. Contrasts between the concave and convex locations of the stripe pattern were obvious in the Young's modulus map, although the topographical map of the film surface appeared almost flat. The concave and convex locations of a polymer film supported by a different micropattern also contrasted clearly. The resulting Young's modulus map showed that the Young's modulus was higher at convex locations than at concave locations. Hence, regions of high and low stiffness can be locally generated based on the shape of the micropattern supporting the film. When cells were cultured on the micropattern-supported films, NIH3T3 fibroblasts preferentially accumulated in convex regions with high Young's moduli. These findings demonstrate that this new technology can regulate regions of high and low surface Young's modulus on a cellular scaffold with high planar resolution, as well as providing a method for directing cellular patterning. © 2017 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 106B: 976-985, 2018.
- Research Article
4
- 10.1002/app.31668
- Jan 5, 2010
- Journal of Applied Polymer Science
An in situ polymerization with a later solution co‐mixing approach was used in the preparation of polymethyl methacrylate (PMMA) matrix composites using hydroxyapatite (HA) nanoparticles and short carbon fibers(C(f)) as reinforcing materials. The microstructures and fracture surface morphologies of the prepared C(f)/HA‐PMMA composite were characterized using XRD, FTIR, SEM, EDS, and FESEM analyses. The mechanical properties of the composites were tested by a universal testing machine. Results show that the surface of nitric acid‐oxidized carbon fibers and lecithin‐treated HA contain new functional groups. Uniform dispersion of short fibers and HA nanoparticles in PMMA matrix is successfully achieved and the mechanical properties of the composites are obviously improved. The flexural strength, flexural modulus, and Young's modulus of the composites reach the maximum value 128.12 MPa, 1.150 GPa, and 4.572 GPa when carbon fiber and HA mass fraction arrive to 4% and 8%, respectively. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010
- Research Article
8
- 10.1016/j.jmst.2024.09.038
- Jun 1, 2025
- Journal of Materials Science & Technology
Towards high stiffness and ductility-The Mg-Al-Y alloy design through machine learning
- Research Article
161
- 10.1016/0921-5093(90)90097-m
- Aug 1, 1990
- Materials Science and Engineering: A
Young's modulus and damping of Ti6Al4V alloy as a function of heat treatment and oxygen concentration
- Research Article
3
- 10.1002/anie.202421427
- Jan 28, 2025
- Angewandte Chemie (International ed. in English)
All-solid-state lithium metal batteries (LMBs) are regarded as next-generation devices for energy storage due to their safety and high energy density. The issues of Li dendrites and poor mechanical compatibility with electrodes present the need for developing solid-state electrolytes with high stiffness and damping, but it is a contradictory relationship. Here, inspired by the superstructure of tooth enamel, we develop a composite solid-state electrolyte composed of amorphous ceramic nanotube arrays intertwined with solid polymer electrolytes. This bionic electrolyte exhibits both high stiffness (Young's modulus=15 GPa, hardness=0.13 GPa) and damping (tanδ=0.08), breaking the trade-off. Thus, this composite electrolyte can not only inhibit Li dendrites growth but also ensure intimate contact with electrodes. Meanwhile, it also exhibits considerable Li+ transference number (0.62) and room temperature ionic conductivity (1.34×10-4 S cm-1), which is attributed to oxygen vacancies of the amorphous ceramic effectively decoupling the Li-TFSI ion pair. Consequently, the assembled Li symmetric battery shows an ultra-stable cycling (>2000 hours at 0.1 mA cm-2 at 60 °C, >500 hours at 0.1 mA cm-2 at 30 °C). Moreover, the LiFePO4/Li and LiNi0.8Co0.1Mn0.1O2/Li all-solid-state full cells both show excellent cycling performance. We demonstrate that this bionic strategy is a promising approach for the development of high-performance solid-state electrolytes.
- Conference Article
4
- 10.1109/icmtma.2010.487
- Mar 1, 2010
As the operation speeds of CNC machine tools are increased, the vibration problem has become a major constraint of manufacturing of precision products. The two important functional requirements of CNC machine tool bed are high structural stiffness and high damping. Conventional metallic materials used for bed structure have high stiffness but low damping. Epoxy concrete materials used for bed structure can satisfy above requirements but their costs are expensive. This paper presents the application of composite concrete bed for CNC machine tool, which is composed of epoxy concrete structure faces and steel fiber cement concrete core. The beds not only satisfy above requirements of CNC machine tool bed but also their costs are lower.
- Research Article
- 10.1299/jsmemmt.2016.11.a03
- Jan 1, 2016
- The Proceedings of The Manufacturing & Machine Tool Conference
For structures of machine tools, weight savings, high stiffness and high damping are important properties. These requirements are not satisfied with only a single material, so composite materials are promising for machine structure. Carbon-fibre-reinforced plastics(CFRP) has high specific stiffness and damping compared to that of steel, but more damping capabilities are required for structural materials of machine tools. This paper proposes a three-dimensional topology optimization method to develop high stiffness and damping composite structures using CFRP and viscoelastic damping materials. To implement optimization algorithm, Abaqus and MATLAB were used. To illustrate the effectiveness of the proposed method, we designed a cantilever beam. The results showed the optimized cantilever beam had higher stiffness and higher damping than the cantilever beam with a single damping layer.
- Research Article
3
- 10.1016/j.physb.2024.416722
- Nov 12, 2024
- Physica B: Condensed Matter
Molecular dynamics simulation of temperature and defect-induced change of the mechanical properties of PBCF-graphene nanosheet
- Research Article
33
- 10.1002/adma.202202305
- Jun 3, 2022
- Advanced Materials
The demand for biomaterials has been increasing along with the increase in the population of elderly people worldwide. The mechanical properties and high wear resistance of metallic biomaterials make them well-suited for use as substitutes or as support for damaged hard tissues. However, unless these biomaterials also have a low Young's modulus similar to that of human bones, bone atrophy inevitably occurs. Because a low Young's modulus is typically associated with poor wear resistance, it is difficult to realize a low Young's modulus and high wear resistance simultaneously. Also, the superelastic property of shape-memory alloys makes them suitable for biomedical applications, like vascular stents and guide wires. However, due to the low recoverable strain of conventional biocompatible shape-memory alloys, the demand for a new alloy system is high. The novel body-centered-cubic cobalt-chromium-based alloys in this work provide a solution to both of these problems. The Young's modulus of <001>-orientedsingle-crystal cobalt-chromium-based alloys is 10-30 GPa, which is similar to that of human bone, and they also demonstrate high wear and corrosion resistance. They also exhibit superelasticity with a huge recoverable strain up to 17.0%. For these reasons, the novel cobalt-chromium-based alloys can be promising candidates for biomedical applications.
- Research Article
8
- 10.1002/app.1993.070470201
- Jan 10, 1993
- Journal of Applied Polymer Science
Young's modulus distributions in the depth direction within injection moldings made from polystyrene have been investigated by empolying two independent techniques. Both methods show that the material close to the surface exhibits relatively high stiffness, whereas at all other depths a lower uniform stiffness exists. The depth dependency of other material characteristics, such as tan δ peaks in the dynamic mechanical thermal analysis spectra and molecular orientation, have been investigated in an attempt to correlate them with the stiffness distributions. It appears that the thermomechanical history of the different regions within the moldings, particularly the stresses acting during flow and the temperature gradients set up during cooling, are primarily responsible for the Young's modulus distributions presented here. © 1993 John Wiley & Sons, Inc.
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