Abstract
The crystal structure of the title compound, [Cu6Br6(C5H5NS)4], consists of a hexanuclear Cu6Br6S4 cluster in which each copper atom is connected to one bromine atom. The sulfur atoms are each connected to three copper atoms via μ3 coordination. Two of the bromine atoms are located on a twofold axis and the clusters are located on a fourfold rotoinversion axis. One unique Cu atom is disordered over two positions; site occupancy factors are 0.6 and 0.4. The other Cu atom is disordered about a twofold rotation axis.
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