Abstract
The title compound, [WIr3(η-C10H15)(μ3-η2-C14H10)2(CO)7], is a mixed-metal cluster with a tetrahedral metal core geometry. One diphenylacetylene ligand is μ3-η2-coordinated to the triiridium face, while the other is μ3-η2-coordinated to a diiridiumtungsten face. The W atom is ligated by a pentamethylcyclopentadienyl ligand and a terminal carbonyl, and the Ir atoms are each ligated by two terminal carbonyls.
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