Abstract
A series of cis-LM(CO) 4 complexes was prepared by reaction of non symmetrical diamines (L=R 1R 2N–(CH 2) n –NH 2, with R 1 and R 2=alkyl groups) with metal carbonyls M(CO) 6, (M=Cr, Mo, W). Only the primary amine of these complexes reacted with mono or dialdehydes, thus leading to mono or dinuclear imine complexes, stabilized by the metal moiety and strongly suggesting that the NH 2–metal bond has a hemilabile character.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.