Abstract

Polycrystalline pyrochlore Lu2Ti2O7 pellets were irradiated with 600keV Kr3+ at room temperature and 723K to a fluence of 4×1015ions/cm2, corresponding to an average ballistic damage dose of 10 displacements per atom in the peak damage region. Irradiation-induced microstructural evolution was examined by grazing incidence X-ray diffraction, and cross-sectional transmission electron microscopy. Incomplete amorphization was observed in the sample irradiated at room temperature due to the formation of nano-crystal which has the identical structure of pyrochlore, and the formation of nano-crystal is attributed to the mechanism of epitaxial recrystallization. However, an ordered pyrochlore phase to a swelling disordered fluorite phase transformation is occurred for the Lu2Ti2O7 sample irradiated at 723K, which is due to the disordering of metal cations and anion vacancies.

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