Abstract
Bis(1-bromo-2-methylpropenyl)mercury, prepared via Me 2CC(Br)Li, was treated with mercuric bromide to give Me 2CC(Br)HgBr. The latter transferred Me 2CC: to olefins, giving isopropylidenecyclopropanes, in sealed tube reactions carried out at 150°C in the presence of an equimolar quantity of diphenylmercury. The Me 2CC(Br)HgBr/Ph 2Hg reagent also reacted with triethylsilane at 150°C to give Et 3SiCHCMe 2 in nearly quantitative yield.
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