Abstract
AbstractWe have been interested in exploiting the highly functionalized oxabicyclo[3.2.1]octadienes that are produced by the cycloaddition of furan and tetrabromocyclopropene as synthetic building blocks. As part of this program, we have prepared non‐racemic derivatives of these adducts containing an α,β‐dibromoenone moiety embedded in the bicyclic framework. Elaboration of this unit has been realized through substitution and palladium‐catalyzed cross‐coupling reactions. Formation of bicyclodecenes has also been accomplished by a chromium‐nickel‐mediated ring closure. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
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