Abstract
The pulsed jet Fourier transform microwave spectrum of the 1:1 complex between CF3Cl and CH3F shows that the two moieties are linked by a Cl···F halogen bond (RCl···F = 2.995 Å). The two symmetric tops CF3 and CH3 undergo free or almost free internal rotations, which alter the "rigid" value of the rotational constant A by almost 1 order of magnitude.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
