Abstract
The theory has been derived and experiments carried out on the effect of triplet exciton exchange on the half-field resonance in (O/AsCH3)+(TCNQ)2−. The half-field resonance is a single Lorentzian line which exhibits a line broadening with increasing temperature in agreement with the effect seen at high field; the thermal activation energies at low and high field are 0.127 and 0.116 eV, respectively, but can not be distinguished statistically. The intensity behavior, however, exhibits an activation energy (effective singlet–triplet splitting) of 0.077 eV at low field compared to that observed at high field of 0.090 eV. This difference cannot be atttributed to a thermal modification of the triplet dipole tensor.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
