Abstract
Assembly of CdCl2 and 3,3′-dimethoxy-2,2′-bipyridine-6,6′-dicarboxylic acid (H2mbpdc) under hydrothermal condition affords a chloride-centered discrete CdII6 cage [Cd6(mbpdc)6Cl]·[H(H2O)14.5] (1), in which a cationic water cluster H+(H2O)10 is present. Our anion-templated assembly system exhibits exclusive encapsulation of Cl− ion, and thus displays potentially applications in the separation of Cl− ion with other halide ions.
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