Abstract

Analytical electron microscopy (AEM) techniques were used to study the growth of intragranular ferrite in Fe-Ni-P alloys. The spatial resolution of the AEM was exploited to gather microchemical information regarding elemental redistribution at ferrite/austenite interfaces in order to determine the growth mechanism for intragranular ferrite. In this alloy system, the growth kinetics are dictated by the bulk diffusion of Ni in austenite. Full equilibrium occurs during intragranular ferrite growth with full partitioning of Ni and P between austenite and ferrite, and chemical equilibrium occurs at the α/γ interface in both phases. A numerical model to simulate ferrite growth was developed based on equilibrium growth considerations. The Ni concentrations and precipitate sizes predicted by the model agree well with those measured by AEM techniques in the experimental alloys. The computer model has been extended to predict the thermal histories of iron meteorites and their parent asteroidal bodies.

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