Abstract

AbstractGroup C+ particles, Group C particles after nano‐modulation, with extremely large specific surface area, have been shown to exhibit extraordinarily good fluidization quality with superiorly high bed expansion, significantly increasing gas holdup in the bed. As a first attempt, Group C+ particles were used as catalysts in a fluidized bed reactor (C‐plus FBR) to evaluate the reaction performance and were compared to that using Group A particles. C‐plus FBR could achieve a much higher reaction conversion, up to 235% of that using Group A particles. The contact efficiency for Group C+ particles is much higher, being 330% more than that for Group A particles. The greater contact efficiency is due to both larger specific surface area and higher bed expansion, providing larger gas–solid interfacial area and longer gas residence time. Conclusively, Group C+ particles with superior fluidization quality and reaction performance do have huge potential in gas‐phase catalytic reactions.

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