Green synthesis of sulfonated cellulose/polyether block amide/polyethylene glycol diacrylate (SC/PEBAX/PEGDA) composite membrane by gamma radiation and sulfonation techniques for battery application

Abstract

Sulfonated cellulose (SC) was successfully prepared through a two-step process of gamma radiation and subsequently sulfonation with potassium metabisulfite of microcrystalline cellulose extracted from sugarcane bagasse. The effect of gamma radiation dose on cellulose showed an increment of oxidation degree, which was evidenced by the intensity ratio of I1718 (carbonyl)/ I2892 (aliphatic) from FTIR analysis. The obtained SC was introduced into polyether block amide/polyethylene glycol diacrylate (PEBAX/PEGDA) polymer matrix as a reinforcement and hydrophilic filler for improving electrolyte affinity and thermal stability of its composite membrane. The increase of SC in PEBAX/PEGDA composite membranes resulted in enhancement of hydrophilicity, electrolyte uptake, and thermal stability compared to pristine composite membranes. However, the excess SC content in the composite membrane exhibited the low physical properties, caused by negligible dispersion on the surface membrane. With the optimum 2.0 wt% SC in PEBAX/PEGDA, the porosity, contact angle and electrolyte uptake capacity was found to be 64.0 %, 12.8° and 37.5 %, respectively. 2.0 wt% SC/PEBAX/PEGDA showed the outstanding thermal stability with negligible shrinkage <10 % at 150 °C whereas pristine PEBAX/PEGDA showed the shrinkage of 29 %. The obtained SC/PEBAX/PEGDA composite membrane is considered as a potential candidate to replace the commercial polyolefin-based separator in lithium-ion batteries.