Abstract
Starting from the glass formation regions in the System HgGeSe it is possible to prepare by addition of Te as a fourth elemental component quaternary glasses in a wide range of composition. For selected series in the systems HgSeGeSeGeSe 2, HgTeGeSeGeSe 2 and HgTeGeTeGeSe 2 the mole volume, glass transition temperature and the electrical direct current conductivity were investigated. Conclusions on structural changes in the glasses were drawn from their dependence on composition. There exist marked differences from glasses in the system PbGeSeTe with analogous composition. The glass forming region HgSeGeSe is extended by addition of HgTe and GeTe, respectively. Furthermore the glass formation range in the system HgGeTe is described for the first time.
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