Abstract

Starting from the glass formation regions in the System HgGeSe it is possible to prepare by addition of Te as a fourth elemental component quaternary glasses in a wide range of composition. For selected series in the systems HgSeGeSeGeSe 2, HgTeGeSeGeSe 2 and HgTeGeTeGeSe 2 the mole volume, glass transition temperature and the electrical direct current conductivity were investigated. Conclusions on structural changes in the glasses were drawn from their dependence on composition. There exist marked differences from glasses in the system PbGeSeTe with analogous composition. The glass forming region HgSeGeSe is extended by addition of HgTe and GeTe, respectively. Furthermore the glass formation range in the system HgGeTe is described for the first time.

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