Abstract
Birefringent crystals (BFCs) have been extensively used in imaging spectrometers, laser devices, and optical components. Seeking new BFCs is important for both fundamental research and industrial applications. Employing first-principles density functional theory, we find that LaOBiS2 (space group: P4/nmm) appearing in the parent phase of the recently discovered BiS2-superconductor exhibits superior birefringence with a maximum value of 2.94, which is 13.4 times larger than the extensively used YVO4 (0.22). Furthermore, LaOBiS2 is an indirect semiconductor with a band gap of 0.9 eV, which is suitable for optical applications. The origin of giant inherent birefringence is also discussed.
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