Geopolymer composites reinforced with silverskin fibers from the coffee industry waste

Abstract

This paper aims to develop sustainable geopolymer composites reinforced with silverskin fibers derived from coffee industry waste. Geopolymer and geopolymer composites were synthesized from blast furnace slags (BFS) with a solid/liquid (alkaline solution) ratio of 1.4. A sodium metasilicate/sodium hydroxide (Na2SiO3/NaOH) mixture at a mass ratio of 2.5 served as the alkaline activator in the geopolymerization process. The composites were evaluated by incorporating 2%, 3%, and 5% by weight of silverskin fibers, which were used in their natural form (SGCn), after treatment with sodium hydroxide (SGCNaOH), and after treatment with sodium hydroxide followed by a steam explosion process (SGCSE).Characterizations of the geopolymer composites included X-ray fluorescence analysis (XRF) for elemental oxide identification, Fourier transform infrared spectroscopy (FTIR) for functional group detection, and thermogravimetric analysis (TGA) for thermal stability assessment. The influence of fibers on the hardness of the geopolymer materials was evaluated using hardness scale measurements. Morphologies, microstructures, and elemental compositions were analyzed through field emission gun scanning electron microscopy with energy dispersive X-ray spectroscopy (FEG-SEM/EDS).The results demonstrate that the incorporation of silverskin fibers, especially those treated with NaOH and subjected to steam explosion, significantly enhances the thermal stability of geopolymer composites. The 5% NaOH-treated fiber composite exhibited the highest Tmax and Tend, indicating superior thermal stability. Additionally, the 5% SGCNaOH composite showed the highest residual mass, further supporting the enhanced thermal stability of these composites.Unlike other fibers, which showed a decrease in hardness, the addition of SGCSE fibers maintains a relatively high hardness in the geopolymer composites. The 2% SGCSE composite exhibited an average hardness equal to that of the pure geopolymer at 66 Shore D.These findings underscore the potential of using treated silverskin fibers to develop more thermally stable, cost-effective, and sustainable geopolymer materials. By utilizing industrial residues and waste, these advanced materials can be applied in the production of construction and building materials, contributing to both environmental sustainability and economic efficiency.