Abstract
The ionic geometries of thioborine HBS + and chlorothioboron ClBS + cations were deduced by applying Franck-Condon analyses to the corresponding He(I) photoelectron bands. The BH and BS bond lengths and the rotational constants of HBS + were respectively found to be 1.197Å, 1.715Å and 0.5603 cm −1 in the X 2π state and 1.185Å, 1.639Å and 0.6089 cm −1 in the A 2∑ + state. As for the ClBS + ion, the BCl and BS bond distances and the rotational constant have values of 1.590Å, 1.716Å and 0.0923 cm −1 respectively. The calculated structural parameters are compared with those from experimental work and ab initio calculations. In addition, the force constants of the two cations have also been determined.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Electron Spectroscopy and Related Phenomena
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
