Abstract

Deuterium modulation of the electron spin echo decay envelope from trapped electrons in γ-irradiated 3-methylpentane-d14 glass at 77 K has been analyzed to give a solvation structure characterized by 18–21 equivalent nearest neighbor deuterons to the electron at a distance of 3.0–3.2 Å and with an isotropic coupling constant of essentially zero. From the structure of 3-methylpentane it is suggested that there are six to seven first solvation shell molecules around the electron.

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