Genetic Mechanism of Geothermal Water in Typical Structural Belts from the Altay and Tianshan to the Kunlun Mountains in Xinjiang: Evidence from Hydrogeochemistry and δ2H–δ18O Isotopes

Hydrochemical and isotopic (2H, 18O and 37Cl) constraints on evolution of geothermal water in coastal plain of Southwestern Guangdong Province, China

Geothermal systems play a crucial role in understanding Earth’s heat dynamics. The Yunkai Uplift in southern China exemplifies a geothermally rich region characterized by ancient lithologies and high heat flow. This study investigates the geochemical characteristics of geothermal waters in the Yunkai Uplift. Both geothermal and non-thermal water samples were collected along the Xinyi–Lianjiang (XL) Fault Zone and the Cenxi–Luchuan (CL) Fault Zone flanking the core of the Yunkai Mountains. Analytical techniques were applied to examine major ions, trace elements, and dissolved CO2 and H2, as well as isotopic characteristics of O, H, Sr, C, and He in water samples, allowing for an investigation of geothermal reservoir temperatures, circulation depths, and mixing processes. The findings indicate that most geothermal waters are influenced by water–rock interactions primarily dominated by granites. The region’s diverse lithologies, change from ancient Caledonian granites and medium–high-grade metamorphic rocks in the central hinterland (XL Fault Zone) to low-grade metamorphic rocks and sedimentary rocks in the western margin (CL Fault Zone). The chemical compositions of geothermal waters are influenced through mixing contacts between diverse rocks of varying ages, leading to distinct geochemical characteristics. Notably, δ13CCO2 values reveal that while some samples exhibit significant contributions from metamorphic CO2 sources, others are characterized by organic CO2 origins. Regional heat flow results from the upwelling of mantle magma, supplemented by radioactive heat generated from crustal granites. Isotopic evidence from δ2H and δ18O indicates that the geothermal waters originate from atmospheric sources, recharged by precipitation in the northern Yunkai Mountains. After infiltrating to specific depths, meteoric waters are heated to temperatures ranging from about 76.4 °C to 178.5 °C before ascending through the XL and CL Fault Zones under buoyancy forces. During their upward migration, geothermal waters undergo significant mixing with cold groundwater (54–92%) in shallow strata. As part of the western boundary of the Yunkai Uplift, the CL Fault Zone may extend deeper into the crust or even interact with the upper mantle but exhibits weaker hydrothermal activities than the XL Fault Zone. The XL Fault Zone, however, is enriched with highly heat-generating granites, is subjected more to both the thermal and mechanical influences of upwelling mantle magma, resulting in a higher heat flow and tension effect, and is more conducive to the formation of geothermal waters. Our findings underscore the role of geotectonic processes, lithological variation, and fault zone activity in shaping the genesis and evolution of geothermal waters in the Yunkai Uplift.

The Mangkang geothermal field, distributed in the Mediterranean–Himalayas geothermal belt, hosts abundant hot springs whose geneses remain unclear. To determine the hydrochemical characteristics, reservoir temperature, circulation and recharge depths, and water–rock interactions of the geothermal water in the geothermal field, this study analyzed hydrochemical compositions and isotopes (2H, 3H, and 18O), conducted a PHREEQC simulation, and established a conceptual model to illustrate the genesis of geothermal resources in the Mangkang field. Based on the study of hot springs in Meipu, Qvzika, and Zulongpu villages and Rumei town, the following results are reported: The orifice temperatures of these hot springs vary between 18 °C and 67.5 °C. The hydrochemical composition analysis results indicate that the geothermal water in the hot springs is of hydrochemical type HCO3-Ca·Mg. Moreover, the geothermal water has high HBO2 and Na+ concentrations, suggesting protracted water runoff and strong water–rock interactions during its evolution. According to the mineral–water solubility equilibrium and silica geothermometers, it is estimated that the reservoir temperature of the Zulongpu hot spring is 47 °C and other hot springs have much higher reservoir temperatures of 116–130 °C. As indicated by geothermal gradients, annual temperatures, and reservoir temperatures, the geothermal water in Meipu and Qvzika villages has the greatest circulation depth, up to 3600–4300 m, followed by that in Rumei town (3700–4000 m) and Zulongpu village (~1500 m). The 2H-18O isotopic analysis of the geothermal surface water revealed that the geothermal water originates from meteoric water. The recharge elevation was inferred to be ~4700–4900 m. Moreover, the low 3H values (<1 Tu) suggest that the geothermal water is older than 40 years. The PHREEQC inverse simulation results indicated that the variation in the hydrochemical composition of the geothermal water results from the precipitation of chalcedony and dolomite, the absorption of NaX, and the loss of CaX2 during migration and storage.

Hydrochemical characteristics, hydrochemical processes and recharge sources of the geothermal systems in Lanzhou City, northwestern China

The southeastern Hainan Island boasts abundant hydrothermal resources, most of which are exposed as thermal springs. Analyzing the hydrochemical characteristics, hydrochemical evolutionary mechanisms, and material transition of these resources is significant for their exploitation and utilization. This study investigated the Nanping geothermal field in southeastern Hainan Island, using five groups of geothermal water samples collected in 2022, as well as seven groups of geothermal water samples, one group of shallow groundwater samples, and one group of surface water samples taken in 2023. Specifically, this study examined water–rock interactions in the geothermal field using the Gibbs model, ion ratios, chloro-alkaline indices (CAIs), and the sodium adsorption ratio (SAR). Moreover, the mineral transfer process in groundwater was analyzed using inverse hydrogeochemical simulation. The results indicate that in the study area the geothermal water temperatures range from 64 °C to 80 °C, pH values from 8.32 to 8.64, and TDS concentrations from 431 mg/L to 623 mg/L. The primary hydrochemical types of geothermal water in the study area include Cl-Na and Cl·HCO3-Na, suggesting low-temperature, slightly alkaline geothermal water. The hydrochemical components of geothermal water in the study area are primarily affected by water–rock interactions. Besides the dissolution of silicate minerals and halite, cation exchange reactions contribute greatly to the formation of Na+ and K+ in geothermal water. Geothermal water receives recharge from the atmospheric precipitation of the Diaoluo Shan area in the northwest of the study area, with the recharge elevation ranging from 967 to 1115 m. The inverse hydrogeochemical simulation results reveal that during the water–rock interactions, silicate minerals, clay minerals, gypsum, and halite dissolve, while quartz and carbonate minerals precipitate. Additionally, these processes are accompanied by cation exchange reactions dominated by the replacement of Na+ in surrounding rocks by Ca2+ in geothermal water. This study can provide a geological basis for the exploitation, utilization, and management of the Nanping geothermal field.

Surface water chemistry at Torfajökull, Iceland—Quantification of boiling, mixing, oxidation and water–rock interaction and reconstruction of reservoir fluid composition

In western Anatolia, Turkey, the continental rift zones of the Büyük Menderes, Küçük Menderes and Gediz were formed by extensional tectonic features striking E-W generally and representing a great number of active geothermal systems, epithermal mineralizations and volcanic rocks from Middle Miocene to recent. The geothermal waters are associated with the faults which strike preferentially NW-SE and NE-SW and locate diagonal to general strike of the rift zones of the Menderes Massif. These NW-SE and NE-SW striking faults were probably generated by compressional tectonic regimes which leads to the deformation of uplift between two extensional rift zones in the Menderes Massif. The one of these rift zones is Gediz which is distinguished by a great number of geothermal waters such as Alaşehir, Kurşunlu, Çamurlu, Pamukkale and Urganlı. The geothermal waters of Alaşehir form the biggest potential in the rift zone of Gediz with a capacity of about 100 to 200 MWe. Geologically, the gneisses from the basement rocks in the study area which are overlain by an Paleozoic to Mesozoic intercalation of mica schists, quartzites and marbles, a Miocene intercalation of conglomerates, sandstones and clay stones and Plio-Quaternary intercalation of conglomerates, sandstones and clay stones discordantly. In the study area, Paleozoic to Mesozoic quartzites and marbles form the reservoir rocks hydrogeologically. The geothermal waters anions with Na+K>Ca>Mg dominant cations and HCO3>Cl> dominant anions are of Na-HCO3 type and can be considered as partial equilibrated waters. According to the results of geochemical thermometers, the reservoir temperatures area of about 185°C in accordance with measured reservoir temperatures. Stabile isotopes of δ18O versus δ2H of geothermal waters of Alaşehir deviate from the meteoric water line showing an intensive water-rock interaction under high temperature conditions. These data are well correlated with the results of the hydrogeochemical analyses which also indicate intensive water-rock interaction and reactions with silicates. In the study area, the geothermal waters of meteoric origin. The infiltration takes place along the Menderes Massif. Due to the deep circulation which is made possible by the deep reaching fault system of the rift zone of Gediz, the meteoric waters are heated by recent subvolcanic activity such as Kula volcano with human foot prints. In the area of Alaşehir, the meteoric waters percolate at fault zones and permeable clastic sediments into the reaction zone of the roof area of a magma chamber (of Kula volcano) situated at a probable depth of 2-4 km where meteoric waters are heated by the cooling magmatic melt and ascend to the surface due to their lower density caused by convection cells. The volatile components of CO2, SO2, HCl, H2S, HB, HF and He out of magma reach the geothermal water reservoir where an equilibrium between altered rocks, gas components and geothermal waters performs. Thus, the geothermal waters ascend in tectonic zones of weakness at the rift zone of the Gediz in terms of hot springs, gases and steams. Finally, the geothermal waters of Alaşehir are distinguished by a 2,0 percent CO2 of productions in geothermal power plants especially.

Geochemical and isotope constraints on the hydrogeology and geochemistry of the geothermal waters in the Shandong Peninsula, China

Geochemical and isotopic characteristics of structurally controlled geothermal and mineral waters of Muğla (SW Turkey)

Abundant geothermal waters have been reported in the Yalabamei, Zhonggu, Erdaoqiao, and Yulingong geothermal areas of the Xianshuihe Fault Zone of western Sichuan, southwestern China. This study focused on the hydrogeochemical evolution, reservoir temperature, and recharge origin of geothermal waters using hydrochemical and deuterium-oxygen (D-O) isotopic studies. Shallow geothermal waters represented by geothermal springs and shallow drilled water wells are divided into two hydrochemical groups: (1) the Ca–Na–HCO3 type in the Erdaoqiao area, and (2) Na–HCO3 in other areas. Deep geothermal waters represented by deep drilled wells are characterized by the Na–Cl–HCO3 type. The major ionic compositions of geothermal water are primarily determined by the water–rock interaction with silicate and carbonate minerals. The reservoir temperatures estimated by multi-geothermometries have a range of 63–150 °C for shallow geothermal water and of 190–210 °C for deep geothermal water, respectively. The δ18O and δD compositions indicated geothermal waters are recharged by meteoric water from the elevation of 2923–5162 m. Based on the aforementioned analyses above, a conceptual model was constructed for the geothermal system in the Xianshuihe fault zone.

Hydrogeochemical characteristics and genesis of the high-temperature geothermal system in the Tashkorgan basin of the Pamir syntax, western China

Constraining the properties of the heat sources of high-temperature hydrogeothermal systems: Evidence from the lithium concentrations of geothermal waters

<p>Hydro-geochemistry of groundwater plays an important role in understanding the characteristics of a geothermal system. Mixing zones of geothermal deep waters and shallow groundwater can be identified through chemical distribution maps and help identify geothermal flow paths. The flow paths can be used to calculate the chemical values of the geothermal water leading to a characterization of the heat source. In combination with knowledge about regional structures, the geochemical distribution can further reveal unknown geothermal zones.</p><p>In the present study, the geochemical distribution of the groundwater is studied from samples collected from shallow and deep wells, with special reference to the regional structures present in the terrain. The study area was selected as a 20 • 20 km area centered around the Padiyathalawa hot spring field in Sri Lanka. From the results, two main geochemical anomalous zones are identified, especially with the increased values of electrical conductivity (EC), total dissolved solids (TDS), and Sulphate distribution maps. Those two zones include the hot spring itself as well as an area in ~10 km distance in the NE direction from the hot spring. Both zones are characterized by crosscutting structures of dolerite dykes and shear zones. Due to the shear zones, there are deep-seated fractures facilitating water flow from deeper layers towards the surface. This uprising water mixes with the shallow groundwater, affecting the general geochemical values of the shallow groundwater system.</p><p>Common minerals in Dolerite in Sri Lanka are Pyroxenes, Feldspar, Ilmenite, Magnetite, and Pyrite with minor amounts of other minerals. The increased EC values in both before mentioned zones relate with higher amounts of iron due to dissolution and mixing processes in regions with fractured Dolerite. Similarly, the increased concentration of Sulphates in the groundwater can be related to Pyrite from the fractured Dolerite, as microbial oxidization of Pyrite leads to origin of Sulphates. The increase of TDS can be interpreted as shallow water mixing with deep geothermal water, which contains a higher amount of minerals from the fractured dolerites.</p><p>The similar geochemical anomalies in those two zones can be associated with cross-cutting Dolerite dikes and existing faults in the shear zones at greater depth, subsequently mixing uprising deep geothermal water with shallow groundwater. A similar geochemistry and tectonic setting suggest similar flow paths from the underground and therefore also similar geothermal conditions at both spots. However, due to the rural and remote region, only one of the two before mentioned areas is known as a hot spring field. Thermal signatures dissipate much more quickly in the shallow groundwater than the mineral composition and might not be significant for measurement. Geochemical signatures of groundwater can therefore be a substantial help to locate geothermal springs, identify source mechanisms and characterize fluid flow paths.</p>

Fluoride occurrence in geothermal water of fault zone area, Southeast China

ABSTRACTLithium (Li) is a valuable resource with significant economic benefits and strategic importance. The extraction of Li from Li‐rich geothermal fluids has low production costs and may be an essential source of Li in the future. The Li contents in the high‐temperature geothermal systems of western Sichuan are high (most exceeding 1 mg/L) and reach the exploration standard. However, the Li source and enrichment processes of high‐temperature geothermal fluids are not well known. Therefore, 30 groups of natural hot springs with Li ≥ 1 mg/L from Batang, Litang, and Kangding high‐temperature geothermal systems were selected to analyse the Li enrichment mechanism in high‐temperature geothermal water. The average exposed temperatures of Batang, Litang, and Kangding geothermal waters were 82.4°C, 53.7°C, and 61.9°C, respectively, and the hydrochemical types were HCO3‐Na. The average concentrations of Li in the geothermal waters of Batang, Litang, and Kangding were 2.32, 3.29, and 3.54 mg/L. Based on the δD and δ18O characteristics, the geothermal waters in the study area originated from meteoric water and snow‐melt water. Magmatic water was also mixed during circulation, with Kangding geothermal water being the most mixed (25.0%). Strong water–rock interactions occurred during geothermal water runoff ascent, including silicate mineral dissolution, geothermal gas dissolution, and cation exchange. The deep reservoir temperatures in the geothermal systems of Batang, Litang, and Kangding were estimated to be 239°C, 200°C, and 242°C, and the shallow reservoir temperatures were 175°C, 86°C, and 116°C. Finally, two Li enrichment mechanisms were proposed: (1) Li in the geothermal waters of Batang and Litang geothermal systems mainly came from the leaching of lepidolite and spodumene during water–rock interactions. (2) Li in the Kangding geothermal system mainly originated from the input of magmatic water. This research deepens the understanding of Li enrichment mechanisms in high‐temperature geothermal systems, which will be helpful for the exploration of geothermal Li resources.