Abstract
Polar and non-polar liquid stationary phases (Apiezon L, tricresyl phosphate and Carbowax 20M) were used for the analysis of C 5–C 8 linear and branched-chain alkyl chlorides. Specific retention volumes, retention index and relative molar heats of solution of alkyl chlorides with respect to the homomorphous alkanes were measured and correlated with molecular structure, in order to permit the identification of isomeric compounds in a mixture. The behaviour of alkyl chlorides was compared with that of the corresponding bromo- and iodoalkanes, on the basis of previously published data.
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