Functions of fluorosurfactants 1: Surface activities-improved and vesicle formation of the short-tailed chain sulfonate salt mixed with a fluorosurfactant

Abstract

Surface-activity of a short-tailed chain hydrocarbon surfactant, heptane-1-sulfonic acid sodium salt (C 7SNa), was studied by using surface tension and conductivity measurements, which the surface-activity was improved largely by the addition of small amount of a fluorosurfactant, 1H,1H,2H,2H,3H,3H,4H,4H-heneicosafluorotetradecylpyridinium iodine (HFTPI). The phase behavior and vesicle formation of C–H/C–F surfactant mixtures in aqueous solutions are similar to ones of cationic–anionic surfactant (catanionic) systems. The birefringent, viscoelastic Lα-phase consisting of unilamellar and multilamellar vesicles can be observed, which were determined by freeze-fracture transmission electron microscopy (FF-TEM) images. The rheological properties of Lα-phase samples were measured. 1H and 19F NMR spectra were measured to monitor the information of self-assemblies of C 7SNa and HFTPI in L 1-phase (spherical micelles) and Lα-phase (vesicles). The results show that the C–H micelles and C–F micelles form in aqueous solutions individually. In Lα-phase (vesicles), the interaction between anionic hydrocarbon (C 7SNa) and cationic fluorocarbon (HFTPI) surfactants exist due to the strong electric static interaction of opposite charge head groups.