Abstract
Eine experimentell einfache, neuartige Friedel-Crafts-Benzylierung verläuft bei moderaten Temperaturen und hat ein verbreitertes Substratspektrum für die Bildung präparativ nützlicher Diarylmethane (siehe Schema). Bei Komplexierung mit BF3⋅OEt2 wirken Hydroxamate als reversible Abgangsgruppen, die hoch reaktive Carbokationen stabilisieren. Selbst desaktivierte Arene und elektronenarme Benzylhydroxamate reagieren glatt unter diesen Bedingungen. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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