Abstract
The silver borophosphate glass system has been investigated using AgI as an additive halide. Electrochemical properties of the prepared glass electrolyte system x.AgI:(100-x).(30Ag2O:(56B2O3-14P2O5)) has been prepared using conventional melt quenching technique. Structural characterization has been employed using XRD diffraction pattern to confirm the amorphous nature of the samples, FT-IR analysis is carried out to study the nature of the chemical bonding and different vibrational modes of structural units present in the composition. The glass transition (Tg) has been measured using TG/DTA technique. Electrical conductivity measurements have been carried out in the temperature range from 303 K to 373 K using complex impedance spectroscopy (CIS). The modulus formalisms along with stretching parameter (β) and decoupling index Rτ are calculated. The conductivity and modulus scaling of the prepared system using different models are studied. The present paper discusses the conduction mechanism and physical parameters of conductivity.
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