Abstract
It is found that when quenched KCl : MnS/Se crystals are irradiated with UV light, S 2 − and Se 2 − molecular ions are formed. By this method these molecular ions were effectively introduced into KCl lattice for the first time. At 8.8 K, such luminescence spectra consist of one or more vibronic series of zero-phonon lines associated with isotope structure and phonon-side bands. The spectroscopic constants ν 00, ω 0″ and ω 0″ x 0″ were calculated for the ground state of Se 2 − ions. On the other hand, from the detailed observation of photochemical reactions in KCl : MnS, it was found that Mn +, Mn 0 and F centers were produced following the formation of S 2 −. From above results, a model for the formation of S 2 − was proposed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
