Abstract
The synthesis of a number of compounds containing the hexakis(fluorosulfato)palladate(IV) anion and the cations Cs+, Ba2+,NO+, and ClO2+ is reported. All compounds are diamagnetic. Also reported is the synthesis of Pd[M(SO3F)6], where M = Pt(IV) and Sn(IV). Here, palladium(II) is found in a regular octahedral environment. Both compounds are paramagnetic, consistent with a 3A2g ground state. Curie–Weiss law behavior is found and ligand field parameters for the Pd(II) derivatives are reported. Vibrational spectra are reported for all new fluorosulfato complexes.
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