Abstract

The effect of fluorine doping on the transport properties of perovskite-related complex oxides based on oxygen-ion conductor Ba4In2Zr2O11 is analyzed. It was shown that fluorine doping allows to increase the oxygen-ion conductivity in the region of low fluorine concentrations due to the result of increase in the mobility of the current carriers. The effect of increasing conductivity is observed for various methods of fluoride doping Ba4In2Zr2O11-0.5xFx[Vo]1-0.5x or Ba4-0.5y[VBa]0.5yIn2Zr2O11-yFy[Vo]1, but more significant for solid solution with unchanged concentration of oxygen vacancies Ba4-0.5y[VBa]0.5yIn2Zr2O11-yFy[Vo]1.

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