Journal of the American Chemical Society | VOL. 108

Fixation and activation of carbon dioxide on aluminum porphyrin. Catalytic formation of a carbamic ester from carbon dioxide, amine, and epoxide

Publication Date Feb 1, 1986


Carbon dioxide is trapped by (5,10,15,20-tetraphenylporphinato) aluminum acetate in the presence of a secondary amine in the form of an aluminum carbamate on the opposite side to the acetate group with respect to the porphyrin plane. Carbon dioxide thus trapped by aluminum porphyrin is activated enough to undergo a catalytic reaction involving secondary amine and epoxide to afford dialkylcarbamic ester under atmospheric pressure at room temperature. 15 references, 2 figures, 2 tables.

Powered ByUnsilo

Aluminum Porphyrin
Activation Of Carbon Dioxide
Carbon Dioxide
Aluminum Acetate
Fixation Of Carbon Dioxide
Secondary Amine
Atmospheric Pressure
Formation Of Ester
Room Temperature
Carbamic Ester

Introducing Weekly Round-ups!Beta

Powered by R DiscoveryR Discovery

Round-ups are the summaries of handpicked papers around trending topics published every week. These would enable you to scan through a collection of papers and decide if the paper is relevant to you before actually investing time into reading it.

Climate change Research Articles published between Aug 08, 2022 to Aug 14, 2022

R DiscoveryAug 15, 2022
R DiscoveryArticles Included:  5

Introduction: There is no consensus on the policies that should be seen as implicitly pricing carbon (see World Bank (2019a) for a discussion). The OE...

Read More

Gender Equality Research Articles published between Aug 08, 2022 to Aug 14, 2022

R DiscoveryAug 15, 2022
R DiscoveryArticles Included:  4

I would like to thank Anna Khakee, Federica Zardo and Ragnar Weilandt for their very useful comments as well as the participants of the workshop of 21...

Read More

Coronavirus Pandemic

You can also read COVID related content on R COVID-19

R ProductsCOVID-19


Creating the world’s largest AI-driven & human-curated collection of research, news, expert recommendations and educational resources on COVID-19

COVID-19 Dashboard

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on “as is” basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The Copyright Law.