Journal of the American Chemical Society | VOL. 108
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Fixation and activation of carbon dioxide on aluminum porphyrin. Catalytic formation of a carbamic ester from carbon dioxide, amine, and epoxide

Publication Date Feb 1, 1986

Abstract

Carbon dioxide is trapped by (5,10,15,20-tetraphenylporphinato) aluminum acetate in the presence of a secondary amine in the form of an aluminum carbamate on the opposite side to the acetate group with respect to the porphyrin plane. Carbon dioxide thus trapped by aluminum porphyrin is activated enough to undergo a catalytic reaction involving secondary amine and epoxide to afford dialkylcarbamic ester under atmospheric pressure at room temperature. 15 references, 2 figures, 2 tables.

Concepts
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Aluminum Porphyrin
Activation Of Carbon Dioxide
Carbon Dioxide
Aluminum Acetate
Fixation Of Carbon Dioxide
Secondary Amine
Atmospheric Pressure
Formation Of Ester
Room Temperature
Carbamic Ester

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