Abstract
A general method of solution for the rovibrational problem for a single large amplitude motion coupled to the overall rotation is presented. The numerical construction of the effective rovibrational Hamiltonian is applicable to any semirigid or flexible model for a large amplitude motion. High-order centrifugal distortion and Coriolis interaction terms generated by the small amplitude vibrations of normal modes are effectively included into the Hamiltonian. The method is illustrated by performing a global fit of the rotational transitions observed in the ground and excited states of some typical large amplitude modes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
